Show us your (carbon nanotube artificial) muscles!

The idea of doctors deploying miniscule robots in your body to diagnose and treat medical conditions is closer to reality today with the development of artificial muscles small and strong enough to push such tiny nano-bots along

Nanostructured electrically conducting biofibres produced using a reactive wet-spinning process

Electrically conducting, robust fibres comprised of both an alginate (Alg) biopolymer and a polypyrrole (PPy) component have been produced using reactive wet-spinning. Using this approach polypyrrole-biopolymer fibres were also produced with single-walled carbon nanotubes (CNTs), added to provide additional strength and conductivity. The fibres produced containing CNTs show a 78% increase in ultimate stress and 25% increase in elongation to break compared to PPy-alginate fibre. These properties are essential for studies involving the use of electrical stimulation to promote nerve regrowth and/or muscle regeneration. The resultant a novel fibres had been evaluated to develop a viable system in incorporating biological entities in the composite biomaterial. These results indicated fibres are biocompatible to living cells

A reactive wet spinning approach to polypyrrole fibres

Electrically conducting, robust fibres comprised of both an alginate (Alg) biopolymer and a polypyrrole (PPy) component have been produced using reactive wet-spinning. Using this approach polypyrrole-biopolymer fibres were also produced with single-walled carbon nanotubes (CNTs), added to provide additional strength and conductivity. SEM images of the PPy-Alg composite fibres clearly show the tubular multifilament form of the alginate fibre impregnated with PPy nanoparticles. The fibres produced containing CNTs show a 78% increase in ultimate stress and 25% increase in elongation to break compared to PPy-alginate fibre. Young\u27s modulus obtained for the PPy-Alg-CNT fibres showed a 30% increase compared to the PPy-alginate fibre. The fibres produced were electrochemically active and capable of electromechanical actuation with a strain of 0.7% produced at a scan rate of 100 mV s-1 of the potential. C 2011 The Royal Society of Chemistry

The use of embedded sensors for the monitoring of adhesive joints in marine environments

A copolymer incorporating polyaniline was used as a sensing medium in the construction of a resistance based humidity sensor. Aniline monomer was polymerised in the presence of poly (butyl acrylate / vinyl acetate) and a copolymer containing polyaniline emeraldine salt was obtained. The sensing medium was then developed by redissolving 1-2 w/w% of the resulting polymer residue in dichloromethane to produce a processable polymer blend solution. Some of this polymer residue was also de-doped in a solution of ammonia, and then washed with distilled water until the waste water had a neutral pH. This residue was then redissolved at 1-2 w/w% in dichloromethane to produce a second processable polymer blend this time containing polyaniline emeraldine base. The final sensor design utilised 125μm polyester insulated platinum wire as conducting electrodes that were dip coated in the emeraldine salt copolymer solution and allowed to dry in a desiccator. The sensor was then dip-coated in a protective barrier layer of the emeraldine base copolymer to prevent over-oxidation and/or de-protonation of the emeraldine salt sensing medium under this coating. The sensors had an overall final thickness of less than 150μm and showed high sensitivity to humidity, low resistance, and good reversibility without hysteresis. Sensors were monitored for 2-probe resistance changes when in contact with water. Calibration curves for each sensor were produced to convert the resistance reading to mass uptake of water. Individual sensors were embedded within Aluminium 5083 / Araldite 2015 adhesive joints to monitor mass uptake of water when exposed to marine environments. Correlations between mass uptake of water and joint strength were made. There are various advantages of such a sensor design. Polymer based thin film humidity sensors have the advantage that the high processability of the material allows for simple fabrication of a range of geometries including smaller sensor designs. The ease of processing gives a low cost sensor, whilst the small size and good mechanical properties gives a robust sensor which has the flexibility to be able to be used in applications where dynamic stresses and strains are encountered. Such sensors may find uses in a number of areas including electronic textiles, food/ electronics packaging and corrosion detection

The effect of geometry and material properties on the performance of a small hydraulic McKibben muscle system

Fluidic McKibben artificial muscles are one of the most popular biomimetic actuators, showing similar static and dynamic performance to skeletal muscles. In particular, their pneumatic version offers high-generated force, high speed and high strain in comparison to other actuators. This paper investigates the development of a small-size, fully enclosed, hydraulic McKibben muscle powered by a low voltage pump. Hydraulic McKibben muscles with an outside diameter of 6 mm and a length ranging from 35 mm to 80 mm were investigated. These muscles are able to generate forces up to 26 N, strains up to 23%, power to mass of 30 W/kg and tension intensity of 1.78 N/mm2 at supply water pressure of 2.5 bar. The effects of injected pressure and inner tube stiffness on the actuation strain and force generation were studied and a simple model introduced to quantitatively estimate force and stroke generated for a given input pressure. This unique actuation system is lightweight and can be easily modified to be employed in small robotic systems where large movements in short time are required

Tri-layer polymer actuators with variable dimensions

The ability of conducting polymer actuators to convert electrical energy into mechanical energy is influenced by manyfactors ranging from the actuators physical dimensions to the chemical structure of the conducting polymer. In order toutilise these actuators to their full potential, it is necessary to explore and quantify the effect of such factors on theoverall actuator performance. The aim of this study is to investigate the effect of various geometrical characteristics suchas the actuator width and thickness on the performance of tri-layer polypyrrole (PPy) actuators operating in air, asopposed to their predecessors operating in an appropriate electrolyte. For a constant actuator length, the influence of theactuator width is examined for a uniform thickness geometry. Following this study, the influence of a varied thicknessgeometry is examined for the optimised actuator width. The performance of the actuators is quantified by examination ofthe force output, tip displacement, efficiency as a function of electrical power and mechanical power, and time constantfor each actuator geometry. It was found that a width of 4mm gave the greatest overall performance without curlingalong the actuator length (which occurred with widths above 4mm). This curling phenomenon increased the rigidity ofthe actuator, significantly lowering the displacement for low loads. Furthermore, it was discovered that by focussing ahigher thickness of PPy material in certain regions of the actuators length, greater performances in various domainscould be achieved. The experimental results obtained set the foundation for us to synthesize PPy actuators with anoptimised geometry, allowing their performance to reach full potential for many cutting applications

Nonlinear single-electron tunneling through individually coated colloid particles at room temperature

Single-electron tunneling (SET) has been observed with nanometer coated colloid gold particles at room temperature. We have made the smallest (3-nm) thiol- and silicon dioxide (SiO2)-coated gold particles, from which we obtained SET signals using a scanning tunneling microscope (STM)images reveal individual particles supported by an atomically flat metal surface. The STM tip is used to obtain SET signals from the individual particles, whose shapes have been characterized. The current-voltage curves of the particles exhibit well-defined Coulomb staircases that resemble those obtained at 4.2 K, indicating a strong Coulomb repulsive interaction at room temperature. The clear Coulomb staircases are due to a nonlinearity in the current steps. We suggest a possible mechanism for the nonlinearity in terms of many-body excitations in the particle. We have also identified the region of the particles, where the SET signal originates, using current-imaging-tunneling spectroscopy. We describe the advantages of using the coated nanometer particles for making devices for room-temperature operations

3D printed flexure hinges for soft monolithic prosthetic fingers

Mechanical compliance is one of the primary properties of structures in nature playing a key role in their efficiency. This study investigates a number of commonly used flexure hinges to determine a flexure hinge morphology, which generates large displacements under a lowest possible force input. The aim of this is to design a soft and monolithic robotic finger. Fused deposition modeling, a low-cost 3D printing technique, was used to fabricate the flexure hinges and the soft monolithic robotic fingers. Experimental and finite element analyses suggest that a nonsymmetric elliptical flexure hinge is the most suitable type for use in the soft monolithic robotic finger. Having estimated the effective elastic modulus, flexion of the soft monolithic robotic fingers was simulated and this showed a good correlation with the actual experimental results. The soft monolithic robotic fingers can be employed to handle objects with unknown shapes and are also potential low-cost candidates for establishing soft and one-piece prosthetic hands with light weight. A three-finger gripper has been constructed using the identified flexure hinge to handle objects with irregular shapes such as agricultural products

Carbon Nanotube Yarn for Fiber-Shaped Electrical Sensors, Actuators, and Energy Storage for Smart Systems

Smart systems are those that display autonomous or collaborative functionalities, and include the ability to sense multiple inputs, to respond with appropriate operations, and to control a given situation. In certain circumstances, it is also of great interest to retain flexible, stretchable, portable, wearable, and/or implantable attributes in smart electronic systems. Among the promising candidate smart materials, carbon nanotubes (CNTs) exhibit excellent electrical and mechanical properties, and structurally fabricated CNT-based fibers and yarns with coil and twist further introduce flexible and stretchable properties. A number of notable studies have demonstrated various functions of CNT yarns, including sensors, actuators, and energy storage. In particular, CNT yarns can operate as flexible electronic sensors and electrodes to monitor strain, temperature, ionic concentration, and the concentration of target biomolecules. Moreover, a twisted CNT yarn enables strong torsional actuation, and coiled CNT yarns generate large tensile strokes as an artificial muscle. Furthermore, the reversible actuation of CNT yarns can be used as an energy harvester and, when combined with a CNT supercapacitor, has promoted the next-generation of energy storage systems. Here, progressive advances of CNT yarns in electrical sensing, actuation, and energy storage are reported, and the future challenges in smart electronic systems considered